Scientists have been working towards developing an efficient nano-hydrogen storage system that could prove to be a massive boon to hydrogen powered vehicles.
Researchers have published a new study in the journal Advanced Material Interfaces wherein they have demonstrated that nanoconfined lithium nitride is a rechargeable, high-performing hydrogen-storage material and their findings could be a huge boost for hydrogen powered vehicles industry.
While hydrogen is one of the best energy carrier, but the hurdle is the development of lightweight solid-state materials for compact, low-pressure storage of hydrogen. Scientists have been looking at complex metal hydrides as a promising class of hydrogen storage materials, but their viability is usually limited by slow hydrogen uptake and release.
Researchers believe that nanoconfinement, which is infiltrating the metal hydride within a matrix of another material such as carbon, could help to speed up the hydrogen uptake and release by shortening diffusion pathways for hydrogen or by changing the thermodynamic stability of the material. The new study however has found that there is an important consequence of nanoconfinement – the presence of internal “nano-interfaces” within nanoconfined hydrides can alter which phases appear when the material is cycled.
The researchers examined the high-capacity lithium nitride (Li3N) hydrogen storage system under nanoconfinement. Using a combination of theoretical and experimental techniques, they showed that the pathways for the uptake and release of hydrogen were fundamentally changed by the presence of nano-interfaces, leading to dramatically faster performance and reversibility. The research appears on the cover of the Feb. 23 edition of the journal Advanced Materials Interfaces.
“The key is to get rid of the undesirable intermediate phases, which slow down the material’s performance as they are formed or consumed. If you can do that, then the storage capacity kinetics dramatically improve and the thermodynamic requirements to achieve full recharge become far more reasonable,” said Brandon Wood, an LLNL materials scientist and lead author of the paper. “In this material, the nano-interfaces do just that, as long as the nanoconfined particles are small enough. It’s really a new paradigm for hydrogen storage, since it means that the reactions can be changed by engineering internal microstructures.”
The Livermore researchers used a thermodynamic modeling method that goes beyond conventional descriptions to consider the contributions from the evolving solid phase boundaries as the material is hydrogenated and dehydrogenated. They showed that accounting for these contributions eliminates intermediates in nanoconfined lithium nitride, which was confirmed spectroscopically.
“There is a direct analogy between hydrogen storage reactions and solid-state reactions in battery electrode materials,” said Tae Wook Heo, another LLNL co-author on the study. “People have been thinking about the role of interfaces in batteries for some time, and our work suggests that some of the same strategies being pursued in the battery community could also be applied to hydrogen storage. Tailoring morphology and internal microstructure could be the best way forward for engineering materials that could meet performance targets.”